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Recombination of molecular ions with electrons at low temperatures
 Kálosi, Ábel ; Plašil, Radek (advisor) ; Kudrna, Pavel (referee)
The aim of this work is the experimental study of recombination of molecular ions with electrons at low temperatures (< 300 K). The work gives an overview of the diagnostic methods, modelling of chemical kinetics, and experimental ap- paratuses Cryo-FALP II and SA-CRDS used in the undertaken measurements. Two processes were studied in the course of this work: state-selective binary disso- ciative recombination of H+ 3 ions in para-H+ 3 and ortho-H+ 3 states, and H2-assisted ternary recombination of H+ 3 . The main result of the state-selective dissociative recombination study is that the rate of recombination in the para-H+ 3 state is at least three times higher than in the ortho-H+ 3 state at 60 K. The study of H2- assisted recombination gave a better understanding of ternary processes of H+ 3 ions and removed further discrepancies between results of afterglow experiments.
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